Asymmetric Allylic Monofluoromethylation and Methylation of Morita–Baylis–Hillman Carbonates with FBSM and BSM by Cooperative Cinchona Alkaloid/FeCl2 Catalysis.
DOI Number:
10.1002/anie.201103748
Reaction Category:
MOP ID:
MOP_0000369
Educt:
(fluoromethylenedisulfonyl)dibenzene, O-protected substituted methyl 2-(hydroxymethyl)acrylate
Product:
3R-substituted methyl 4-fluoro-2-methylene-4,4-bis(phenylsulfonyl)butanoate
Catalyst:
iron(II) chloride, tetraisopropoxytitanium, 1,4-Bis[(9S)-10,11-dihydro-6′-methoxycinchonan-9-yl]-9,10-anthracenedione
Cas No:
176298-44-5
Associated Product from Buchler GmbH:
Dihydroquinidine Base
Cas No:
1435-55-8