Enantioselective Nitrene Transfer to Hydrocinnamyl Alcohols and Allylic Alcohols Enabled by Systematic Exploration of the Structure of Ion-Paired Rhodium Catalysts.
DOI Number:
10.1021/jacs.4c07117
Reaction Category:
Educt:
3-phenylpropan-1-ol, heptafluorobutyl sulfamate
Product:
heptafluorobutyl (3-hydroxy-1-phenylpropyl)sulfamate
Catalyst:
pentafluorophenyl-bis(2,2,2-trifluoroacetato-κO)-iodine, rhodium catalyst, (9S)-1-[[3,5-bis(1,1-dimethylethyl)phenyl]methyl]-10,11-dihydro-9-hydroxy-6′-methoxy-cinchonanium bromide
Cas No:
1439215-88-9
Associated Product from Buchler GmbH:
Dihydroquinidine Base
Cas No:
1435-55-8