Organocatalytic asymmetric allylic benzylborylation via fluoride-assisted catalytic generation of α-boryl carbanionic intermediates.

DOI Number:

10.26434/chemrxiv-2024-7ld1j
Link to literature

Reaction Category:

allylic benzylborylation | Further reactions

Educt:

((4-chlorophenyl)(3,3,4,4-tetramethyl-1l3,2,5-bromadioxolan-1-yl)methyl)trimethylsilane, methyl 2-(fluoro(phenyl)methyl)acrylate

Product:

methyl (3S,4S)-4-(4-chlorophenyl)-2-methylene-3-phenyl-4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)butanoate

Catalyst:

1,4-Bis(9-O-dihydroquinidinyl)phthalazine ((DHQD)2PHAL)

Cas No:

140853-10-7

Associated Product from Buchler GmbH:

1,4-Bis(9-O-dihydroquinidinyl)phthalazine ((DHQD)2PHAL)

Cas No:

140853-10-7