Chiral betaine-mediated asymmetric peroxidation-kinetic resolution cascade for the synthesis of optically pure peroxides.

DOI Number:

10.31635/ccschem.023.202302759

Reaction Category:

Educt:

(E)-(4-((trifluoromethyl)sulfonyl)but-3-en-1-yl)benzene, (2-hydroperoxypropan-2-yl)benzene

Product:

(S)-(2-((4-phenyl-1-((trifluoromethyl)sulfonyl)butan-2-yl)peroxy)propan-2-yl)benzene

Catalyst:

(9S)-9-[(6-chloro-2,5-diphenyl-4-pyrimidinyl)oxy]-1- [[2′-(1,1-dimethylethoxy)[1,1′:3′,1′′-terphenyl]-5′-yl]methyl]- 6′-hydroxy-Cinchonanium inner salt

Cas No:

1998156-73-2

Cas No:

70877-75-7