Chiral betaine-mediated asymmetric peroxidation-kinetic resolution cascade for the synthesis of optically pure peroxides.
DOI Number:
10.31635/ccschem.023.202302759
Reaction Category:
Educt:
(E)-(4-((trifluoromethyl)sulfonyl)but-3-en-1-yl)benzene, (2-hydroperoxypropan-2-yl)benzene
Product:
(S)-(2-((4-phenyl-1-((trifluoromethyl)sulfonyl)butan-2-yl)peroxy)propan-2-yl)benzene
Catalyst:
(9S)-9-[(6-chloro-2,5-diphenyl-4-pyrimidinyl)oxy]-1- [[2′-(1,1-dimethylethoxy)[1,1′:3′,1′′-terphenyl]-5′-yl]methyl]- 6′-hydroxy-Cinchonanium inner salt
Cas No:
1998156-73-2
Associated Product from Buchler GmbH:
Cupreidine Base
Cas No:
70877-75-7