Enantioselective Bromoaminocyclization Using Amino–Thiocarbamate Catalysts.

DOI Number:

10.1021/ja201627h
Link to literature

Reaction Category:

Bromination | Bromoaminocyclization

MOP ID:

MOP_0000551

Educt:

4-nitro-N-(4-phenylpent-4-en-1-yl)benzenesulfonamide, N-Bromosuccinimide

Product:

(R)-2-(bromomethyl)-1-((4-nitrophenyl)sulfonyl)-2-phenylpyrrolidine

Catalyst:

(8α,9R)-9-[N-(2,6-diethoxyphenyl)carbamothioate]-6′-methoxy-cinchonan-9-ol

Cas No:

1304755-91-6

Associated Product from Buchler GmbH:

Quinine Base

Cas No:

130-95-0