Rational design and atroposelective synthesis of N–N axially chiral compounds.

DOI Number:

10.1016/j.chempr.2021.07.013
Link to literature

Reaction Category:

Atropisomer synthesis

Educt:

ethyl 4-benzoyl-1-((methoxycarbonyl)amino)-2-methyl-5-phenyl-1H-pyrrole-3-carboxylate, benzyl 2-(((tert-butoxycarbonyl)oxy)methyl)acrylate

Product:

ethyl 4-benzoyl-1-((2-((benzyloxy)carbonyl)allyl)(methoxycarbonyl)amino)-2-methyl-5-phenyl-1H-pyrrole-3-carboxylate

Catalyst:

Quinidine Base

Cas No:

56-54-2

Associated Product from Buchler GmbH:

Quinidine Base

Cas No:

56-54-2