Synthesis of α-Quaternary β-Lactams via Copper-Catalyzed Enantioconvergent Radical C(sp3)−C(sp2) Cross-Coupling with Organoboronate Esters.
DOI Number:
10.1002/anie.202214709
Reaction Category:
Educt:
tertiary alkyl bromides, organoboronate esters
Product:
α-quaternary chiral β-lactams
Catalyst:
N-[(9S)-6′-methoxycinchonan-9-yl]-2-(1-methylethyl)-8-quinolinesulfonamide
Cas No:
2882204-93-3
Associated Product from Buchler GmbH:
Quinine Base
Cas No:
130-95-0