Enantioselective synthesis of chiral sulfones by hydrogen-bonding/organophotoredox co-catalyzed asymmetric sulfonylation.
DOI Number:
10.1039/D3QO00324H
Reaction Category:
Educt:
(2E)-1-(3,5-Dimethyl-1H-pyrazol-1-yl)-2-buten-1-one, 3,5-Diethyl 4-cyclohexyl-1,4-dihydro-2,6-dimethyl-3,5-pyridinedicarboxylate, DABCO-bis(sulfur dioxide)
Product:
(3S)-3-(cyclohexylsulfonyl)-1-(3,5-dimethyl-1H-pyrazol-1-yl)-1-butanone
Catalyst:
3-[[3,5-Bis(trifluoromethyl)phenyl]amino]-4- [[(8α,9S)-10,11-dihydro-6′-methoxycinchonan- 9-yl]amino]-3-Cyclobutene-1,2-dione
Cas No:
1352957-59-5
Associated Product from Buchler GmbH:
Dihydroquinine Base
Cas No:
522-66-7