Continuous Enantioselective α-Alkylation of Ketones via Direct Photoexcitation.
DOI Number:
10.1021/acs.joc.4c00759
Reaction Category:
MOP ID:
MOP_0000369
Educt:
ketones, diethyl 2-bromomalonate
Product:
diethyl (R)-2-(3,3-dimethyl-9-oxo-1,5-dioxaspiro[5.5]undecan-8-yl)malonate
Catalyst:
(8α,9S)-6′-Methoxy-2′-phenylcinchonan-9-amine
Cas No:
1278571-62-2
Associated Product from Buchler GmbH:
Quinine Base
Cas No:
130-95-0