Highly enantioselective conjugate addition of 1-bromonitroalkanes to α, β-unsaturated ketones catalyzed by 9-amino-9-deoxyepiquinine.

DOI Number:

10.1016/j.tet.2009.03.055
Link to literature

Reaction Category:

Michael | Michael Addition

RXNO ID:

RXNO_0000009

Educt:

α,β-unsaturated ketones, 1-bromonitroalkanes

Product:

substituted 4-bromo-4-nitrobutanoyl

Catalyst:

(8α,9S)-6′-Methoxycinchonan-9-amine

Cas No:

168960-95-0

Associated Product from Buchler GmbH:

Quinine Base

Cas No:

130-95-0