Direct Noncovalent Activation of α,β-Unsaturated Aldehydes for the Stereodivergent Synthesis of Substituted Cyclohexenes.

DOI Number:

10.1002/chem.201701315
Link to literature

Reaction Category:

[4+2]-Cycloaddition | Cycloaddition

MOP ID:

MOP_0000565

Educt:

α,β-unsaturated aldehydes, nitroalkenes, acetic anhydride

Product:

subsituted cyclohexenes

Catalyst:

N-[(1R,2S)-2,3-dihydro-2-hydroxy-1H-inden-1-yl]-N′-[(8α,9R)-6′-methoxycinchonan-9-yl]-thiourea

Cas No:

2096444-52-7

Associated Product from Buchler GmbH:

Quinine Base

Cas No:

130-95-0