Remote Control of Axial Chirality: Aminocatalytic Desymmetrization of N-Arylmaleimides via Vinylogous Michael Addition.
DOI Number:
10.1021/ja505610k
Reaction Category:
RXNO ID:
RXNO_0000009
Educt:
3-ethylcyclohex-2-en-1-one, N-(2-tert-Butylphenyl)maleimide
Product:
(R)-1-(2-(tert-butyl)phenyl)-3-((R)-1-(3-oxocyclohex-1-en-1-yl)ethyl)pyrrolidine-2,5-dione
Catalyst:
N-Boc-L-phenylglycine, (8α,9S)-6′-Methoxycinchonan-9-amine
Cas No:
168960-95-0
Associated Product from Buchler GmbH:
Quinine Base
Cas No:
130-95-0